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Polyurethane

Polyurethane Specifications.

The chemistry

Polyurethane is based on the polyaddition reaction between a polyol and a diisocyanate — an exothermic reaction. Polymerization is influenced by the type of polyol and isocyanate components as well as additives. Cell formation is obtained by adding a blowing agent (halogenated hydrocarbons with a low boiling point, or water, which reacts with isocyanate groups to form CO₂).

Density classes

Material classDensityTypical uses
Solid PU elastomers1,200 kg/m³Print rollers, cast elastomers, RIM solid plastics
Microcellular foams & elastomers800 kg/m³Coatings, adhesives, sealants, elastomers
Low-density foamsfrom ~6 kg/m³Footwear soles, integral-skin, bedding & upholstery, packaging
Rigid insulation foam (KPI)30–55 kg/m³Spray, panel and pour-in-place insulation

Thermal conductivity — rigid PU vs other insulation (equal performance thickness)

Insulation materialK-value W/m·°CThickness (mm)
Rigid polyurethane foam0.01934
Phenolic foam0.03742
Expanded polystyrene0.04048
Expanded cork0.04550
Fibre glass0.04540
Reinforced cement0.05090
Glass mineral wool0.05555
Foam glass0.06069

Thermal conductivity — rigid PU vs other insulation (equal performance thickness)

Insulation materialK-value W/m·°CThickness (mm)
Rigid polyurethane foam0.01934
Phenolic foam0.03742
Expanded polystyrene0.04048
Expanded cork0.04550
Fibre glass0.04540
Reinforced cement0.05090
Glass mineral wool0.05555
Foam glass0.06069

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